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erizing deeper burial, if a mechanism exists to flush magnesium-bearing fluids through the beds. Mineral dolomite has a 12% to 13% smaller volume than calcite per alkali cation. Thus dolomitization likely increases porosity and contributes to the sugary texture of dolomite. The dolomite problem and primary dolomite Dolomite is supersaturated in normal seawater by a factor of greater than ten, but dolomite is not seen to precipitate in the oceans. Likewise, geologists have not been successful at precipitating dolomite from seawater at normal temperatures and pressures in laboratory experiments. This is likely due to a very high activation energy for nucleating crystals of dolomite. The magnesium ion is a relatively small ion, and it acquires a tightly bound hydration shell when dissolved in water. In other words, the magnesium ion is surrounded by a clump of water molecules that are strongly attracted to its positive charge. Calcium is a larger ion and this reduces the strength of binding of its hydration shell, so it is much easier for a calcium ion than a magnesium ion to shed its hydration shell and bind to a growing crystal. It is also more difficult to nucleate a seed crystal of ordered dolomite than disordered hi
